This site archives articles that include guidance on how to handle volunteers who seem to cause trouble. Some articles of particular note:
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5 Healthy Ways to Handle Difficult Volunteers
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How to Handle a Difficult Volunteer Leader
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8 Myths About Difficult Volunteers
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When Helping Hands Hurt your Cause
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The Break-Up: How to Say No to Volunteers
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Strategies for Dealing with Unreliable Volunteers
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How to Fire a Volunteer and Live to Tell About It